Learning target: I can use a particle model of melting to predict how a pure substance will behave as it gains energy, and use that prediction with test data to choose and justify a design that meets criteria and constraints.
Read the problem, the criteria and constraints, and the facts about four pack materials. In Part A, use your particle model to predict how each pack will behave before you look at the test results. In Part B, evaluate the options against every criterion and constraint. In Part C, make and defend a recommendation. Work with a partner, but write your own Part C.
You will need: This worksheet, Pencil, Calculator (optional)
A county health clinic runs a mobile van that carries vaccines to rural schools and farmworker communities. On summer days the air outside can reach 35 °C or more. The vaccines ride in insulated coolers for up to 10 hours. Most vaccines must stay between 2 °C and 8 °C: too warm and they slowly lose strength, and some are ruined if they get close to freezing. The clinic wants a reusable cold pack, a sealed pouch filled with one pure substance, that will hold the coolers in that range. Engineers often call these phase-change packs, because they work by changing state.
| Option | Material | What it is | Melting point |
|---|---|---|---|
| A | Water (ice) | The familiar pure substance | 0 °C |
| B | Tetradecane | A colorless, waxy compound made from petroleum | about 6 °C |
| C | Hexadecane | A similar waxy compound with longer molecules | about 18 °C |
| D | Dry ice (solid carbon dioxide) | Turns straight from solid to gas | −78.5 °C (sublimes) |
| Option | Temperature it holds near while changing state | Too cold, in range or too warm? |
|---|---|---|
| A: water ice | ||
| B: tetradecane | ||
| C: hexadecane | ||
| D: dry ice |
An engineer tested each option in identical coolers on a 35 °C day, with a temperature logger beside the vaccine boxes. She then tested different numbers of tetradecane packs.
| Option | Packs per cooler, and where they were stored overnight | Coldest reading at the vaccines (°C) | Hours with vaccines between 2 °C and 8 °C | Cost per pack | Notes |
|---|---|---|---|---|---|
| A | 2 packs, from the −18 °C freezer | -5 | 4 | $4 | Vaccines below 0 °C for the first 2 hours, then about 1-3 °C |
| B | 2 packs, from the 3 °C refrigerator | 4 | 11 | $18 | Held near 6 °C until about hour 11, then rose above 8 °C |
| C | 2 packs, from the 3 °C refrigerator | 4 | 1 | $20 | Rose above 8 °C within the first hour, then held near 18 °C |
| D | 1 kg, bought that morning | -40 | 0 | $3 per kg, each trip | Vaccines frozen; gas pushed the cooler lid open |
| Tetradecane packs per cooler | Hours with vaccines between 2 °C and 8 °C |
|---|---|
| 1 | 6 |
| 2 | 11 |
| 3 | 16 |
| Option | At least 10 h in range? (1) | Never below 2 °C? (2) | Safe in a closed van? (3) | Re-solidified with clinic equipment? (4) | Still allowed? |
|---|---|---|---|---|---|
| A: water ice | |||||
| B: tetradecane | |||||
| C: hexadecane | |||||
| D: dry ice |
Think of the heating curve from class. While a pure solid melts at a steady pressure, its temperature stays flat at the melting point even though energy keeps flowing in. A phase-change pack is that flat step put to work. For each option ask: where is its flat step, and is that temperature between 2 °C and 8 °C? Then ask: can the clinic make it solid again (is the fridge or freezer colder than its melting point)?
Some vaccines must be shipped frozen, far below the 2-8 °C range, and some lab samples must stay below −60 °C. Explain which of the four materials could serve a shipment that must stay below −60 °C, what new safety constraints the clinic would have to add, and why that material cannot simply be refrozen in an ordinary freezer. Then explain why a pack that sublimates instead of melting is a problem in a closed van, using the particle model of a gas.